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Pyroxferroite

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Title: Pyroxferroite  
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Subject: Tranquillityite, Armalcolite, Inosilicates, Glaucochroite, Knebelite
Collection: Calcium Minerals, Inosilicates, Iron Minerals, Manganese Minerals, Pyroxene Group, Triclinic Minerals
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Pyroxferroite

Pyroxferroite
Pyroxferroite
General
Category Inosilicate
Formula
(repeating unit)
(Fe2+,Ca)SiO3
Strunz classification 09.DO.05
Identification
Color Yellow
Crystal system Triclinic, space group P1 or P1; a = 0.66213 nm, b = 0.75506 nm, c = 1.73806 nm, α = 114.267°, β = 82.684°, γ = 94.756°, Z = 14
Cleavage Good on (010), poor on (001)
Mohs scale hardness 4.5–5.5
Luster Vitreous
Streak White
Specific gravity 3.68–3.76 g/cm3 (measured)
Optical properties Biaxial (+)
Refractive index nα = 1.748–1.756
nβ = 1.750–1.758
nγ = 1.767–1.768
Pleochroism Faint; pale yellow to yellow-orange
2V angle 34–40°
References [1][2][3][4]

Pyroxferroite (Fe2+,Ca)SiO3 is a single chain inosilicate. It is mostly composed of iron, silicon and oxygen, with smaller fractions of calcium and several other metals.[1] Together with armalcolite and tranquillityite, it is one of the three minerals which were discovered on the Moon. It was then found in Lunar and Martian meteorites as well as a mineral in the Earth's crust. Pyroxferroite can also be produced by annealing synthetic clinopyroxene at high pressures and temperatures. The mineral is metastable and gradually decomposes at ambient conditions, but this process can last billions of years.

Contents

  • Etymology 1
  • Occurrence 2
  • Synthesis 3
  • Properties 4
  • References 5

Etymology

Pyroxferroite is named from pyroxene and ferrum (Latin for iron), as the iron-rich analogue of pyroxmangite.[1] The word pyroxene, in turn comes from the Greek words for fire (πυρ) and stranger (ξένος). Pyroxenes were named this way because of their presence in volcanic lavas, where they are sometimes seen as crystals embedded in volcanic glass; it was assumed they were impurities in the glass, hence the name "fire strangers". However, they are simply early-forming minerals that crystallized before the lava erupted.[5][6]

Occurrence

Pyroxferroite was first discovered in 1969 in lunar rock samples from the Sea of Tranquility during the Apollo missions.[4] Together with armalcolite and tranquillityite, it is one of the three minerals which were first found on the Moon.[7] Later, pyroxferroite was detected in Lunar and Martian meteorites recovered in Oman. It also occurs in the Earth's crust, in association with clinopyroxene, plagioclase, ilmenite, cristobalite, tridymite, fayalite, fluorapatite and potassic feldspar, and forms series with pyroxmangite. Pyroxferroite has been found in the Isanago mine, in Kyoto Prefecture, Japan; near Iva, Anderson County, South Carolina, USA; from Vaaster Silfberg, Vaarmland, Sweden; and Lapua, Finland.[1][2] In the original lunar samples, pyroxferroite was associated with similar minerals, but also with troilite which is rare on Earth, but is common on the Moon and Mars.[4]

Synthesis

Synthetic pyroxferroite crystals can be produced by compressing synthetic clinopyroxene (composition Ca0.15Fe0.85SiO3) to a pressure in the range of 10–17.5 kbar and heating it to 1130–1250 °C. It is metastable at low temperatures and pressures: at pressures below 10 kbar pyroxferroite converts to a mixture of olivine, pyroxene and a silicon dioxide phase, whereas at low temperatures, it transforms to a clinopyroxene.[4] The presence of cristobalite, vesicular texture and some other petrographic observations indicate that the lunar pyroxferroite was produced upon rapid cooling from low-pressure and high-temperature (volcanic) conditions, i.e. that the mineral is metastable. However, the conversion rate is very slow and pyroxferroite can exist at low temperatures for periods longer than 3 billion years.[8]

Crystal structure. Colors: blue – Fe, gray – Si, red – oxygen.

Properties

The crystal structure of pyroxferroite contains silicon-oxygen chains with a repeat period of seven SiO4 tetrahedra. These chains are separated by polyhedra where a central metal atom is surrounded by 6 or 7 oxygen atoms; there are 7 inequivalent metal polyhedra in the unit cell. The resulted layers are parallel to (110) planes in pyroxferroite, whereas they are parallel to (100) planes in pyroxenes.[9]

Chemical composition of pyroxferroite can be decomposed into elementary oxides as follows: FeO (concentration 44–48%), SiO2(45–47%), CaO (4.7–6.1%), MnO (0.6–1.3%), MgO (0.3-1%), TiO2 (0.2–0.5%) and Al2O3 (0.2–1.2%). Whereas magnesium is usually present at about 0.8%, in some samples it had an undetectably low concentration.[4]

References

  1. ^ a b c d "Pyroxferroite" (PDF). Handbook of Mineralogy. Retrieved 2009-08-07. 
  2. ^ a b "Pyroxferroite". Mindat.org. Retrieved 2010-08-07. 
  3. ^ "Pyroxferroite". Webmineral. Retrieved 2010-08-07. 
  4. ^ a b c d e Chao, E. C. T.; et al. (1970). "Pyrox-ferrite, a new calcium-bearing iron silicate from Tranquillity Base". Geochimica et Cosmochimica Acta Supplement 1: 65.  
  5. ^ Concise English Dictionary, Wordsworth Editions, 2007 ISBN 1-84022-497-5 p. 757
  6. ^ William Alexander Deer, Robert Andrew Howie, J. Zussman Single-chain silicates, Volume 2, Geological Society, 1997, ISBN 1-897799-85-3, p. 3
  7. ^ Lunar Sample Mineralogy, NASA
  8. ^ Lindsley, D. H.; Burnham, C. W. (1970). "Pyroxferroite: Stability and X-ray Crystallography of Synthetic Ca0.15Fe0.85SiO3 Pyroxenoid". Science 168 (3929): 364–7.  
  9. ^ Burnham, C. W. "The crystal structure of pyroxferroite from Mare Tranquillitatis". Proceedings of the Lunar Science Conference 2: 47.  
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